Steric Effects in the Chemisorption of Vibrationally Excited Methane on Nickel

Bruce Yoder s thesis outlines his investigation of the dissociative chemisorption of methane (CH4) on a nickel single crystal. In this work Bruce uses a molecular beam and infrared laser techniques to prepare methane in excited rovibrational states. The excited methane molecules are aligned relative...

पूर्ण विवरण

में बचाया:
ग्रंथसूची विवरण
मुख्य लेखक: Yoder, Bruce L.
स्वरूप: Livre numérique
भाषा:Anglais
प्रकाशित: Berlin, Heidelberg : Springer Berlin Heidelberg [20..].
Cham : Springer Nature
संस्करण:2012.
श्रृंखला:Springer Theses, Recognizing Outstanding Ph.D. Research
ऑनलाइन पहुंच:Accès sur la plateforme de l'éditeur
Accès sur la plateforme Istex
Accès Université d'Orléans
Accès INSA CVL
टिप्पणी: Archives Springer e-books (Licence nationale)
Archives Springer e-books (Licence nationale)
Autres localisations: Voir dans le Sudoc
Edition sous un autre format:• Steric Effects in the Chemisorption of Vibrationally Excited Methane on Nickel, Texte imprimé, 9783642276781
• Steric Effects in the Chemisorption of Vibrationally Excited Methane on Nickel, Texte imprimé, 9783642276804
• Steric Effects in the Chemisorption of Vibrationally Excited Methane on Nickel, Texte imprimé, 9783642276781
• Steric Effects in the Chemisorption of Vibrationally Excited Methane on Nickel, Texte imprimé, 9783662521618
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505 1 |a Introduction Experimental Setup State specific preparation and alignment of gas-phase reagents State-resolved steric effects in methane chemisorption on Ni(100) State-resolved steric effects in CH4(v3) dissociation on Ni(110) Summary and Outlook 
506 |a Accès en ligne pour les établissements français bénéficiaires des licences nationales 
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506 |a Conditions particulières de réutilisation pour les bénéficiaires des licences nationales. https://www.licencesnationales.fr/springer-nature-ebooks-contrat-licence-ln-2017 
520 |a Bruce Yoder s thesis outlines his investigation of the dissociative chemisorption of methane (CH4) on a nickel single crystal. In this work Bruce uses a molecular beam and infrared laser techniques to prepare methane in excited rovibrational states. The excited methane molecules are aligned relative to the target nickel surface. Bruce describes the discovery and exploration of a previously unknown steric effect in the dissociation reaction between a vibrationally excited methane molecule and a nickel crystal. From these studies we see that methane molecules are up to twice as reactive when the vibration is aligned parallel rather than perpendicular to the surface. This discovery will help guide the development of detailed predictive models of methane chemisorption, which in turn may lead to better catalysts for the synthesis of several industrially relevant chemicals, including hydrogen fuel from natural gas 
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