Steric Effects in the Chemisorption of Vibrationally Excited Methane on Nickel
Bruce Yoder s thesis outlines his investigation of the dissociative chemisorption of methane (CH4) on a nickel single crystal. In this work Bruce uses a molecular beam and infrared laser techniques to prepare methane in excited rovibrational states. The excited methane molecules are aligned relative...
Wedi'i Gadw mewn:
| Prif Awdur: | |
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| Fformat: | Livre numérique |
| Iaith: | Anglais |
| Cyhoeddwyd: |
Berlin, Heidelberg :
Springer Berlin Heidelberg
[20..].
Cham : Springer Nature |
| Rhifyn: | 2012. |
| Cyfres: | Springer Theses, Recognizing Outstanding Ph.D. Research
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| Mynediad Ar-lein: | Accès sur la plateforme de l'éditeur Accès sur la plateforme Istex Accès Université d'Orléans Accès INSA CVL |
| Nodyn: |
Archives Springer e-books (Licence nationale) Archives Springer e-books (Licence nationale) |
| Autres localisations: | Voir dans le Sudoc |
| Edition sous un autre format: | • Steric Effects in the Chemisorption of Vibrationally Excited Methane on Nickel, Texte imprimé, 9783642276781 • Steric Effects in the Chemisorption of Vibrationally Excited Methane on Nickel, Texte imprimé, 9783642276804 • Steric Effects in the Chemisorption of Vibrationally Excited Methane on Nickel, Texte imprimé, 9783642276781 • Steric Effects in the Chemisorption of Vibrationally Excited Methane on Nickel, Texte imprimé, 9783662521618 |
| Crynodeb: | Bruce Yoder s thesis outlines his investigation of the dissociative chemisorption of methane (CH4) on a nickel single crystal. In this work Bruce uses a molecular beam and infrared laser techniques to prepare methane in excited rovibrational states. The excited methane molecules are aligned relative to the target nickel surface. Bruce describes the discovery and exploration of a previously unknown steric effect in the dissociation reaction between a vibrationally excited methane molecule and a nickel crystal. From these studies we see that methane molecules are up to twice as reactive when the vibration is aligned parallel rather than perpendicular to the surface. This discovery will help guide the development of detailed predictive models of methane chemisorption, which in turn may lead to better catalysts for the synthesis of several industrially relevant chemicals, including hydrogen fuel from natural gas |
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| Disgrifiad o'r Eitem: | Archives Springer e-books (Licence nationale) Archives Springer e-books (Licence nationale) |
| ISBN: | 9783642276798 |
| ISSN: | 2190-5061 |
| Mynediad: | Accès en ligne pour les établissements français bénéficiaires des licences nationales Accès soumis à abonnement pour tout autre établissement Conditions particulières de réutilisation pour les bénéficiaires des licences nationales. https://www.licencesnationales.fr/springer-nature-ebooks-contrat-licence-ln-2017 |