High- and Low-Valent tris-N-Heterocyclic Carbene Iron Complexes : A Study of Molecular and Electronic Structure

Carola Vogel s PhD thesis focuses on the synthesis, and structural and spectroscopic characterization of the first high valent iron nitride complexes. In her interdisciplinary and collaborative research Carola also describes the reactivity studies of a unique iron (V) nitride complex with water. The...

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Bibliografiske detaljer
Hovedforfatter: Vogel, Carola S.
Format: Livre numérique
Sprog:Anglais
Udgivet: Berlin, Heidelberg : Springer Berlin Heidelberg [20..].
Cham : Springer Nature
Udgivelse:2012.
Serier:Springer Theses, Recognizing Outstanding Ph.D. Research
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Kommentar: Archives Springer e-books (Licence nationale)
Archives Springer e-books (Licence nationale)
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Edition sous un autre format:• High- and Low-Valent tris-N-Heterocyclic Carbene Iron Complexes, Texte imprimé, 9783642272530
• High- and Low-Valent tris-N-Heterocyclic Carbene Iron Complexes, Texte imprimé, 9783642272554
• High- and Low-Valent tris-N-Heterocyclic Carbene Iron Complexes, Texte imprimé, 9783642272530
• High- and Low-Valent tris-N-Heterocyclic Carbene Iron Complexes, Texte imprimé, 9783662509050
Beskrivelse
Summary:Carola Vogel s PhD thesis focuses on the synthesis, and structural and spectroscopic characterization of the first high valent iron nitride complexes. In her interdisciplinary and collaborative research Carola also describes the reactivity studies of a unique iron (V) nitride complex with water. These studies show that quantitative yields of ammonia are given at ambient conditions. High valent iron nitride and oxo species have been proposed as key intermediates in many bio-catalytic transformations, but until now these species have proven exceedingly challenging to isolate and study. Iron complexes in high oxidation states can thus serve as models for iron-containing enzymes to help us understand biological systems or aid our development of more efficient industrial catalysts
Emne beskrivelse:Archives Springer e-books (Licence nationale)
Archives Springer e-books (Licence nationale)
ISBN:9783642272547
ISSN:2190-5061
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