Design, construction and research application of a differential electrochemical mass spectrometer (DEMS)

Sean Ashton's doctoral thesis, which he finished at the Technical University in Munich, describes the challenge of constructing a Differential Electrochemical Mass Spectrometer instrument (DEMS). DEMS combines an electrochemical cell with mass spectrometry via a membrane interface, allowing gas...

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Hlavní autor: Ashton, Sean James, 19..-
Médium: Livre numérique
Jazyk:Anglais
Vydáno: Berlin, Heidelberg : Springer Berlin Heidelberg [20..].
Cham : Springer Nature
Vydání:1st ed. 2012.
Edice:Springer Theses, Recognizing Outstanding Ph.D. Research
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Poznámka: Archives Springer e-books (Licence nationale)
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Edition sous un autre format:• Design, Construction and Research Application of a Differential Electrochemical Mass Spectrometer (DEMS), Texte imprimé, 9783642305498
• Design, Construction and Research Application of a Differential Electrochemical Mass Spectrometer (DEMS), Texte imprimé, 9783642305511
• Design, Construction and Research Application of a Differential Electrochemical Mass Spectrometer (DEMS), Texte imprimé, 9783642435072
• Design, Construction and Research Application of a Differential Electrochemical Mass Spectrometer (DEMS), Texte imprimé, 9783642305498
Popis
Shrnutí:Sean Ashton's doctoral thesis, which he finished at the Technical University in Munich, describes the challenge of constructing a Differential Electrochemical Mass Spectrometer instrument (DEMS). DEMS combines an electrochemical cell with mass spectrometry via a membrane interface, allowing gaseous and volatile electrochemical reaction species to be monitored online.The thesis carefully introduces the fuel cell electrocatalyst development concerns before reviewing the pertinent literature on DEMS. This is followed by the presentation and discussion of the new extended design, including a thorough characterization of the instrument. The capabilities of the new setup are demonstrated in two research studies: The methanol oxidation reaction on Pt and PtRu catalysts, and the electrochemical corrosion of fuel cell catalyst supports. Despite both topics having long since been studied, new insights can be obtained through careful investigations with the new DEMS instrument that are of great, general interest. The thesis and the instrument thus show the way for future investigations in the field
Popis jednotky:Archives Springer e-books (Licence nationale)
Archives Springer e-books (Licence nationale)
ISBN:9783642305504
ISSN:2190-5061
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