Epoxidations and hydroperoxidations of a,b-unsaturated ketones : an approach through asymmetric organocatalysis
Corinna Reisinger has developed a new organocatalytic asymmetric epoxidation of cyclic and acyclic a,b-unsaturated ketones. In this thesis, Corinna documents her methodology, using primary amine salts as catalysts, and hydrogen peroxide as an inexpensive and environmentally benign oxidant. She descr...
Kaydedildi:
| Yazar: | |
|---|---|
| Materyal Türü: | Livre numérique |
| Dil: | Anglais |
| Baskı/Yayın Bilgisi: |
Berlin, Heidelberg :
Springer Berlin Heidelberg
[20..].
Cham : Springer Nature |
| Edisyon: | 1st ed. 2012. |
| Seri Bilgileri: | Springer Theses, Recognizing Outstanding Ph.D. Research
|
| Online Erişim: | Accès sur la plateforme de l'éditeur Accès sur la plateforme Istex Accès Université d'Orléans Accès INSA CVL |
| Not: |
Archives Springer e-books (Licence nationale) Archives Springer e-books (Licence nationale) |
| Autres localisations: | Voir dans le Sudoc |
| Edition sous un autre format: | • Epoxidations and Hydroperoxidations of a,b-Unsaturated Ketones, Texte imprimé, 9783642281174 • Epoxidations and Hydroperoxidations of a,b-Unsaturated Ketones, Texte imprimé, 9783642281198 • Epoxidations and Hydroperoxidations of a,b-Unsaturated Ketones, Texte imprimé, 9783642435331 • Epoxidations and Hydroperoxidations of a,b-Unsaturated Ketones, Texte imprimé, 9783642281174 |
İçindekiler:
- Background Asymmetric Organocatalysis Catalytic Asymmetric Epoxidation of Electron-Deficient Olefins Synthesis and Relevance of 3-Hydroxy-1,2-dioxolanes and 1,2-Dioxolanes Objectives of this Ph.D. Work Results and Discussion Catalytic Asymmetric Epoxidation of Cyclic Enones Catalytic Asymmetric Epoxidation and Hydroperoxidation of Acyclic Enones Synthetic Transformations of Optically Active a,ß-Epoxy Ketones and 3-Hydroxy-1,2-dioxolanes Summary and Conclusions Mechanistic Considerations Preparation of Starting Materials Catalyst Synthesis Summary Outlook Experimental Part General Experimental Conditions Catalytic Asymmetric Epoxidation of Cyclic Enones Catalytic Asymmetric Hydroperoxidation and Epoxidation of Acyclic Enones Synthetic Transformations of Optically Active Products Preparation of Starting Materials Catalyst Synthesis