The siamese-twin porphyrin and Its copper and nickel complexes : a non-innocent twist
This thesis describes the first and long-sought successful synthesis of a new pyrazole-expanded porphyrin, a higher analog of porphyrin. This "Siamese-Twin Porphyrin" provides two conjoined porphyrin-like coordination spheres, thus being able to accommodate two metal ions within the same l...
Kaydedildi:
| Yazar: | |
|---|---|
| Materyal Türü: | Livre numérique |
| Dil: | Anglais |
| Baskı/Yayın Bilgisi: |
Cham :
Springer International Publishing
[20..].
Cham : Springer Nature |
| Edisyon: | 1st ed. 2013. |
| Seri Bilgileri: | Springer Theses, Recognizing Outstanding Ph.D. Research
|
| Online Erişim: | Accès sur la plateforme de l'éditeur Accès sur la plateforme Istex Accès Université d'Orléans Accès INSA CVL |
| Not: |
Archives Springer e-books (Licence nationale) Archives Springer e-books (Licence nationale) |
| Autres localisations: | Voir dans le Sudoc |
| Edition sous un autre format: | • The Siamese-Twin Porphyrin and Its Copper and Nickel Complexes: A Non-Innocent Twist, Texte imprimé, 9783319016733 • The Siamese-Twin Porphyrin and Its Copper and Nickel Complexes: A Non-Innocent Twist, Texte imprimé, 9783319016757 • The Siamese-Twin Porphyrin and Its Copper and Nickel Complexes: A Non-Innocent Twist, Texte imprimé, 9783319016733 • The Siamese-Twin Porphyrin and Its Copper and Nickel Complexes: A Non-Innocent Twist, Texte imprimé, 9783319343655 |
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| 082 | |a 546 | ||
| 100 | 1 | |a Blusch, Lina K. | |
| 245 | 1 | 0 | |a The siamese-twin porphyrin and Its copper and nickel complexes : |b a non-innocent twist |c by Lina K. Blusch. |
| 250 | |a 1st ed. 2013. | ||
| 260 | |a Cham : |b Springer International Publishing. | ||
| 260 | |a Cham : |b Springer Nature, |c [20..]. | ||
| 490 | 0 | |a Springer Theses, Recognizing Outstanding Ph.D. Research |x 2190-5061 | |
| 500 | |a Archives Springer e-books (Licence nationale) | ||
| 500 | |a Archives Springer e-books (Licence nationale) | ||
| 505 | 1 | |a General Introduction Objective Route to the Siamese-Twin Porphyrin Siamese-Twin Porphyrin LH4 Nickel and Copper Complexes Redox Properties Summary and Outlook Experimental Section APENDIX: Crystallographic Details Details on DFT calculations | |
| 506 | |a Accès en ligne pour les établissements français bénéficiaires des licences nationales | ||
| 506 | |a Accès soumis à abonnement pour tout autre établissement | ||
| 506 | |a Conditions particulières de réutilisation pour les bénéficiaires des licences nationales. https://www.licencesnationales.fr/springer-nature-ebooks-contrat-licence-ln-2017 | ||
| 520 | |a This thesis describes the first and long-sought successful synthesis of a new pyrazole-expanded porphyrin, a higher analog of porphyrin. This "Siamese-Twin Porphyrin" provides two conjoined porphyrin-like coordination spheres, thus being able to accommodate two metal ions within the same ligand. In her thesis, Lina Blusch not only explains the challenging synthesis and characterization of the ligand system, but also its application to the synthesis of homo- and hetero-bimetallic Ni and Cu complexes. She observes interesting metal-metal-interactions in the complexes, that lead to a non-innocent multistep redox chemistry. The ligand system and its complexes show an intriguing twisted geometry, giving rise to helical chirality and other fascinating properties. This study explores the first steps and opens up a new chemistry of expanded porphyrins with the potential to biomimetic applications | ||
| 776 | 0 | |t The Siamese-Twin Porphyrin and Its Copper and Nickel Complexes: A Non-Innocent Twist |b Texte imprimé |z 9783319016733 | |
| 776 | 0 | |t The Siamese-Twin Porphyrin and Its Copper and Nickel Complexes: A Non-Innocent Twist |b Texte imprimé |z 9783319016757 | |
| 776 | 0 | |t The Siamese-Twin Porphyrin and Its Copper and Nickel Complexes: A Non-Innocent Twist |b Texte imprimé |z 9783319016733 | |
| 776 | 0 | |t The Siamese-Twin Porphyrin and Its Copper and Nickel Complexes: A Non-Innocent Twist |b Texte imprimé |z 9783319343655 | |
| 856 | 4 | |q PDF |u https://doi.org/10.1007/978-3-319-01674-0 |z Accès sur la plateforme de l'éditeur | |
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| 856 | 4 | |5 452349901:747814082 |u https://ezproxy.univ-orleans.fr/login?url=https://dx.doi.org/10.1007/978-3-319-01674-0 |z Accès Université d'Orléans | |
| 856 | 4 | |5 180339901:750830425 |u https://ezproxy.insa-cvl.fr/login?qurl=https://dx.doi.org/10.1007/978-3-319-01674-0 |z Accès INSA CVL | |
| 997 | |0 947338 |1 Livre numérique |a Ressource numérique |b INSA |b ENSA |c 0/Bibliothèque numérique/ |c 1/Bibliothèque numérique/Autre ressource numérique/ | ||