The siamese-twin porphyrin and Its copper and nickel complexes : a non-innocent twist
This thesis describes the first and long-sought successful synthesis of a new pyrazole-expanded porphyrin, a higher analog of porphyrin. This "Siamese-Twin Porphyrin" provides two conjoined porphyrin-like coordination spheres, thus being able to accommodate two metal ions within the same l...
সংরক্ষণ করুন:
| প্রধান লেখক: | |
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| বিন্যাস: | Livre numérique |
| ভাষা: | Anglais |
| প্রকাশিত: |
Cham :
Springer International Publishing
[20..].
Cham : Springer Nature |
| সংস্করন: | 1st ed. 2013. |
| মালা: | Springer Theses, Recognizing Outstanding Ph.D. Research
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| অনলাইন ব্যবহার করুন: | Accès sur la plateforme de l'éditeur Accès sur la plateforme Istex Accès Université d'Orléans Accès INSA CVL |
| টীকা: |
Archives Springer e-books (Licence nationale) Archives Springer e-books (Licence nationale) |
| Autres localisations: | Voir dans le Sudoc |
| Edition sous un autre format: | • The Siamese-Twin Porphyrin and Its Copper and Nickel Complexes: A Non-Innocent Twist, Texte imprimé, 9783319016733 • The Siamese-Twin Porphyrin and Its Copper and Nickel Complexes: A Non-Innocent Twist, Texte imprimé, 9783319016757 • The Siamese-Twin Porphyrin and Its Copper and Nickel Complexes: A Non-Innocent Twist, Texte imprimé, 9783319016733 • The Siamese-Twin Porphyrin and Its Copper and Nickel Complexes: A Non-Innocent Twist, Texte imprimé, 9783319343655 |
| সংক্ষিপ্ত: | This thesis describes the first and long-sought successful synthesis of a new pyrazole-expanded porphyrin, a higher analog of porphyrin. This "Siamese-Twin Porphyrin" provides two conjoined porphyrin-like coordination spheres, thus being able to accommodate two metal ions within the same ligand. In her thesis, Lina Blusch not only explains the challenging synthesis and characterization of the ligand system, but also its application to the synthesis of homo- and hetero-bimetallic Ni and Cu complexes. She observes interesting metal-metal-interactions in the complexes, that lead to a non-innocent multistep redox chemistry. The ligand system and its complexes show an intriguing twisted geometry, giving rise to helical chirality and other fascinating properties. This study explores the first steps and opens up a new chemistry of expanded porphyrins with the potential to biomimetic applications |
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| উপাদানের বিবরণ: | Archives Springer e-books (Licence nationale) Archives Springer e-books (Licence nationale) |
| আইসবিএন: | 9783319016740 |
| আইএসএসএন: | 2190-5061 |
| প্রবেশাধিকার: | Accès en ligne pour les établissements français bénéficiaires des licences nationales Accès soumis à abonnement pour tout autre établissement Conditions particulières de réutilisation pour les bénéficiaires des licences nationales. https://www.licencesnationales.fr/springer-nature-ebooks-contrat-licence-ln-2017 |