Neodymium Based Ziegler Catalysts Fundamental Chemistry
Even though Ziegler catalysts have been known for almost half a century, rare earth metals (Ln), particularly neodymium (Nd)-based Ziegler catalyst systems, only came into the focus of industrial and academic research well afterthelargescaleapplicationoftitanium,cobaltandnickelcatalystsystems. Asadi...
Gorde:
| Egile nagusia: | |
|---|---|
| Formatua: | Livre numérique |
| Hizkuntza: | Anglais |
| Argitaratua: |
Berlin, Heidelberg :
Springer Berlin Heidelberg
[20..].
Cham : Springer Nature |
| Edizioa: | 1st ed. 2006. |
| Saila: | Advances in Polymer Science
204 |
| Gaiak: | |
| Sarrera elektronikoa: | Accès sur la plateforme de l'éditeur Accès sur la plateforme Istex Accès Université d'Orléans Accès INSA CVL |
| Oharra: |
Archives Springer e-books (Licence nationale) Archives Springer e-books (Licence nationale) |
| Autres localisations: | Voir dans le Sudoc |
| Edition sous un autre format: | • Neodymium based Ziegler catalysts - fundamental chemistry, volume editor: Oskar Nuyken, Berlin, Springer, 2006, 1 vol. (X-287 p.), Advances in polymer science, 3-540-34809-3 • Neodymium Based Ziegler Catalysts - Fundamental Chemistry, Texte imprimé, 9783642071126 • Neodymium Based Ziegler Catalysts - Fundamental Chemistry, Texte imprimé, 9783540825210 • Neodymium based Ziegler catalysts - fundamental chemistry, volume editor: Oskar Nuyken, Berlin, Springer, 2006, 1 vol. (X-287 p.), Advances in polymer science, 3-540-34809-3 |
| Gaia: | Even though Ziegler catalysts have been known for almost half a century, rare earth metals (Ln), particularly neodymium (Nd)-based Ziegler catalyst systems, only came into the focus of industrial and academic research well afterthelargescaleapplicationoftitanium,cobaltandnickelcatalystsystems. Asadirectconsequenceofthelaterecognitionofthetechnologicalpotentialof rareearthmetalZieglercatalysts,thesesystemshaveattractedmuchattention. Considerable progress has been made in this ?eld as a result of intensive workperformed during the last fewyears. Worthmentioning is thestructural identi?cation of a variety of Ln/Al heterobimetallic complexes and the role of alkyl aluminum cocatalysts in molar mass control. Furthermore, a deeper understanding ofthe polymerization mechanism, suchas theliving character of neodymium-catalyzed diene polymerization associated with the reversible transfer of living polymer chains between Nd and Al, was revealed quite - cently. In spite of the vast number of patents and publications mainly issued duringthelastdecade,acomprehensivereviewthatcoversthescienti?caswell as the patent literature has been missing until now. In this volume we try to review the available literature by two independent approaches to Nd and Ln-catalyzed diene polymerizations. In the ?rst part of thevolume,whichisentitled Neodymium-Based Ziegler/NattaCatalystsand their Application in Diene Polymerization , a polymer chemist s view is given with strong emphasis on Nd-based catalyst systems. Also technological and industrialaspectsofNd-catalyzeddienepolymerizationsareaddressed.Inthe secondpartofthevolume,whichisentitled Rare-EarthMetalsandAluminum Getting Close in Ziegler-type Organometallics , a more organometallic p- spective isgivenandLn-based catalystsystems areaddressed. Bythesynopsis of these different perspectives, the reader will comprehend the complexity of Ln-based Ziegler catalyst systems and their application to the polymerization of dienes. This volume also gives a description ofthe evolution in Nd-catalyzed po- merization of dienes from the early works to the current state of the art |
|---|---|
| Alearen deskribapena: | Archives Springer e-books (Licence nationale) Archives Springer e-books (Licence nationale) |
| ISBN: | 9783540348115 |
| ISSN: | 1436-5030 |
| Sartu: | Accès en ligne pour les établissements français bénéficiaires des licences nationales Accès soumis à abonnement pour tout autre établissement Conditions particulières de réutilisation pour les bénéficiaires des licences nationales. https://www.licencesnationales.fr/springer-nature-ebooks-contrat-licence-ln-2017 |