Total Synthesis of Plakortide E and Biomimetic Synthesis of Plakortone B
In his thesis, Xiao-yu Sun conducts the first total synthesis of all possible stereoisomers of plakortide E and also confirms the absolute configuration of natural plakortide E. Xiao-yu Sun subsequently converts Plakortide E methyl ester to plakortone B in a biomimetic conversion. Construction and f...
שמור ב:
| מחבר ראשי: | |
|---|---|
| פורמט: | Livre numérique |
| שפה: | Anglais |
| יצא לאור: |
Berlin, Heidelberg :
Springer Berlin Heidelberg
[20..].
Cham : Springer Nature |
| מהדורה: | 2012. |
| סדרה: | Springer Theses, Recognizing Outstanding Ph.D. Research
|
| גישה מקוונת: | Accès sur la plateforme de l'éditeur Accès sur la plateforme Istex Accès Université d'Orléans Accès INSA CVL |
| הערה: |
Archives Springer e-books (Licence nationale) Archives Springer e-books (Licence nationale) |
| Autres localisations: | Voir dans le Sudoc |
| Edition sous un autre format: | • Total Synthesis of Plakortide E and Biomimetic Synthesis of Plakortone B, Texte imprimé, 9783642271946 • Total Synthesis of Plakortide E and Biomimetic Synthesis of Plakortone B, Texte imprimé, 9783642442117 • Total Synthesis of Plakortide E and Biomimetic Synthesis of Plakortone B, Texte imprimé, 9783642271960 • Total Synthesis of Plakortide E and Biomimetic Synthesis of Plakortone B, Texte imprimé, 9783642271946 |
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| 100 | 1 | |a Sun, Xiao-Yu. | |
| 245 | 1 | 0 | |a Total Synthesis of Plakortide E and Biomimetic Synthesis of Plakortone B |c by Xiao-Yu Sun. |
| 250 | |a 2012. | ||
| 260 | |a Berlin, Heidelberg : |b Springer Berlin Heidelberg. | ||
| 260 | |a Cham : |b Springer Nature, |c [20..]. | ||
| 490 | 0 | |a Springer Theses, Recognizing Outstanding Ph.D. Research |x 2190-5061 | |
| 500 | |a Archives Springer e-books (Licence nationale) | ||
| 500 | |a Archives Springer e-books (Licence nationale) | ||
| 505 | 1 | |a Introduction Results and Discussion Conclusion Experimental Section References Appendix I Appendix II | |
| 506 | |a Accès en ligne pour les établissements français bénéficiaires des licences nationales | ||
| 506 | |a Accès soumis à abonnement pour tout autre établissement | ||
| 506 | |a Conditions particulières de réutilisation pour les bénéficiaires des licences nationales. https://www.licencesnationales.fr/springer-nature-ebooks-contrat-licence-ln-2017 | ||
| 520 | |a In his thesis, Xiao-yu Sun conducts the first total synthesis of all possible stereoisomers of plakortide E and also confirms the absolute configuration of natural plakortide E. Xiao-yu Sun subsequently converts Plakortide E methyl ester to plakortone B in a biomimetic conversion. Construction and functionalization of cyclic peroxides are notoriously difficult due to the very low O-O bond dissociation energy. Plaktoride E is isolated from the Jamaican marine sponge platorits halichondrioides and contains a five-membered peroxide ring, with oxygen atoms linked to tertiary C4 and C6 centers. The methodology used for synthesizing highly substituted cyclic peroxides is novel and useful, and not only extends the field of Pd-catalyzed reactions, but also provides a convenient synthetic approach for the preparation of the 1,2-dioxolanes series. Plakortide E and plakortone B are bioactive, which means that the synthetic studies on them and their analogs are pivotal in drug discovery | ||
| 776 | 0 | |t Total Synthesis of Plakortide E and Biomimetic Synthesis of Plakortone B |b Texte imprimé |z 9783642271946 | |
| 776 | 0 | |t Total Synthesis of Plakortide E and Biomimetic Synthesis of Plakortone B |b Texte imprimé |z 9783642442117 | |
| 776 | 0 | |t Total Synthesis of Plakortide E and Biomimetic Synthesis of Plakortone B |b Texte imprimé |z 9783642271960 | |
| 776 | 0 | |t Total Synthesis of Plakortide E and Biomimetic Synthesis of Plakortone B |b Texte imprimé |z 9783642271946 | |
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