Late Transition Metal-Carboryne Complexes : Synthesis, Structure, Bonding, and Reaction with Alkenes and Alkynes
In this thesis, Zaozao Qiu shows that transition metals can mediate or catalyze cycloaddition and coupling reactions of carboryne with alkynes or alkenes. These reactions afford benzocarboranes, alkenylcarboranes or dihydrobenzocarboranes, and are powerful strategies to assemble useful complex molec...
Salvato in:
| Autore principale: | |
|---|---|
| Natura: | Livre numérique |
| Lingua: | Anglais |
| Pubblicazione: |
Berlin, Heidelberg :
Springer Berlin Heidelberg
[20..].
Cham : Springer Nature |
| Edizione: | 2012. |
| Serie: | Springer Theses, Recognizing Outstanding Ph.D. Research
|
| Accesso online: | Accès sur la plateforme de l'éditeur Accès sur la plateforme Istex Accès Université d'Orléans Accès INSA CVL |
| Nota: |
Archives Springer e-books (Licence nationale) Archives Springer e-books (Licence nationale) |
| Autres localisations: | Voir dans le Sudoc |
| Edition sous un autre format: | • Late Transition Metal-Carboryne Complexes, Texte imprimé, 9783642243608 • Late Transition Metal-Carboryne Complexes, Texte imprimé, 9783642435027 • Late Transition Metal-Carboryne Complexes, Texte imprimé, 9783642243622 • Late Transition Metal-Carboryne Complexes, Texte imprimé, 9783642243608 |
Sommario:
- Introduction Nickel-1,2-o-Carboryne Complexes Nickel-Mediated Coupling Reactions of 1,2-o-Carboryne with Alkenes Nickel-Mediated/Catalyzed Three-Component Cycloaddition Reaction of 1,2-o-Carboryne/Arynes, Alkenes, and Alkynes Nickel-Catalyzed Regioselective [2+2+2] Cycloaddition of 1,2-o-Carboryne with Alkynes Palladium/Nickel-Cocatalyzed [2+2+2] Cycloaddition of 1,3-o-Carboryne with Alkynes Conclusion Experimental Section