Metal-oxo and metal-peroxo species in catalytic oxidations

The present volume is a description of the current knowledge on the different metal-oxo and metal-peroxo species which are involved in catalytic oxidations. These highly reactivity metal-oxygen species are the key intermediates in heme or non-heme oxygenases, as well as in metal-catalyzed oxidations...

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Dades bibliogràfiques
Autor principal: Meunier, Bernard, 1947-...., chimiste
Altres autors: Adam, Waldemar, 1937- (Director editorial)
Format: Livre numérique
Idioma:Anglais
Publicat: Berlin [etc.] : Springer [20..].
Cham : Springer Nature
Col·lecció:Structure and bonding 97
Matèries:
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Archives Springer e-books (Licence nationale)
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Edition sous un autre format:• Metal-Oxo and Metal-Peroxo Species in Catalytic Oxidations, Texte imprimé, 9783540669432
• Metal-Oxo and Metal-Peroxo Species in Catalytic Oxidations, Texte imprimé, 9783662156629
• Metal-oxo and metal-peroxo species in catalytic oxidations, vol. ed.: B. Meunier. With contributions by W. Adam ..., 2000, Berlin, Springer, 1 vol. (VIII, 323 p.), Structure and bonding, 3-540-66943-4
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505 0 |a Active Iron-Oxo and Iron-Peroxo Species in Cytochromes P450 and Peroxidases; Oxo-Hydroxo Tautomerism with Water-Soluble Metalloporphyrins -- Nucleophilicity of Iron-Peroxo Porphyrin Complexes -- Characterization of High-Valent Oxo-Metalloporphyrins -- Characterization, Orbital Description, and Reactivity Patterns of Transition-Metal Oxo Species in the Gas Phase -- Quantum Chemical Studies on Metal-Oxo Species Related to the Mechanisms of Methane Monooxygenase and Photosynthetic Oxygen Evolution -- Characterization and Properties of Non-Heme Iron Peroxo Complexes -- Copper-Dioxygen and Copper-Oxo Species Relevant to Copper Oxygenases and Oxidases -- Rhenium-Oxo and Rhenium-Peroxo Complexes in Catalytic Oxidations -- Structure, Reactivity, and Selectivity of Metal-Peroxo Complexes Versus Dioxiranes -- Nature of Activated Bleomycin. 
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520 |a The present volume is a description of the current knowledge on the different metal-oxo and metal-peroxo species which are involved in catalytic oxidations. These highly reactivity metal-oxygen species are the key intermediates in heme or non-heme oxygenases, as well as in metal-catalyzed oxidations. The accumulated knowledge on these reactive entities will facilitate a better understanding of the different intermediates involved in the catalytic cycles of enzymes like cytochromes P-450, non-heme oxygenases, copper oxygenases, in the oxidation of water by the manganese-center of Photosystem II, in the chemistry of dioxiranes and also in DNA cleavage performed by activated bleomycin. The description of these metal-oxo and metal-peroxo species is based on physico-chemical data, reactivity results and also on theoretical calculations. 
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