Transition metal and rare earth compounds : excited states, transitions, interactions II
There exists a large literature on the spectroscopic properties of copper(II) com- 9 pounds. This is due to the simplicity of the d electron configuration, the wide variety of stereochemistries that copper(II) compounds can adopt, and the f- xional geometric behavior that they sometimes exhibit [1]....
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|---|---|
| Format: | Livre numérique |
| Sprog: | Anglais |
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Berlin [etc.] :
Springer
[20..].
Cham : Springer Nature |
| Serier: | Topics in current chemistry
214 |
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Archives Springer e-books (Licence nationale) Archives Springer e-books (Licence nationale) |
| Autres localisations: | Voir dans le Sudoc |
| Edition sous un autre format: | • Transition Metal and Rare Earth Compounds, Texte imprimé, 9783540679769 • Transition Metal and Rare Earth Compounds, Texte imprimé, 9783642087578 • Transition Metal and Rare Earth Compounds, Texte imprimé, 9783662146910 |
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| 020 | |a 9783540444749 (PDF) | ||
| 041 | 0 | |a eng | |
| 082 | |a 547 | ||
| 100 | 1 | |a Yersin, Hartmut. | |
| 245 | 1 | 0 | |a Transition metal and rare earth compounds : |b excited states, transitions, interactions |n II |c [edited by] Hartmut Yersin. |
| 260 | |a Berlin [etc.] : |b Springer. | ||
| 260 | |a Cham : |b Springer Nature, |c [20..]. | ||
| 490 | 0 | |a Topics in current chemistry |v 214 |x 1436-5049 | |
| 500 | |a Archives Springer e-books (Licence nationale) | ||
| 500 | |a Archives Springer e-books (Licence nationale) | ||
| 505 | 0 | |a Upconversion Processes in Transition Metal and Rare Earth Metal Systems -- Geometric and Electronic Information from the Spectroscopy of Six-Coordinate Copper(II) Compounds -- Low-Lying Electronic States and Photophysical Properties of Organometallic Pd(II) and Pt(II) Compounds. Modern Research Trends Presented in Detailed Case Studies. | |
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| 506 | |a Conditions particulières de réutilisation pour les bénéficiaires des licences nationales. https://www.licencesnationales.fr/springer-nature-ebooks-contrat-licence-ln-2017 | ||
| 520 | |a There exists a large literature on the spectroscopic properties of copper(II) com- 9 pounds. This is due to the simplicity of the d electron configuration, the wide variety of stereochemistries that copper(II) compounds can adopt, and the f- xional geometric behavior that they sometimes exhibit [1]. The electronic and geometric properties of a molecule are inexorably linked and this is especially true with six-coordinate copper(II) compounds which are subject to a Jahn-T- ler effect.However,the spectral-structural correlations that are sometimes d- wn must often be viewed with caution as the information contained in a typical solution UV-Vis absorption spectrum of a copper(II) compound is limited. Meaningful spectral-structural correlations can be obtained in a related series of compounds where detailed spectroscopic data is available. In the fol- 4 lowing sections two such series are examined; the six-coordinate CuF and 6 2+ Cu(H O) ions doped as impurities in single crystal hosts.Using low tempera- 2 6 ture polarized optical spectroscopy and electron paramagnetic resonance, a very detailed picture can be drawn about the geometry of these ions in both their ground and excited electronic states. We then compare the spectrosco- cally determined structural data with that obtained from X-ray diffraction or EXAFS measurements. | ||
| 650 | |a Métaux de transition |x Composés | ||
| 650 | |a Métaux des terres rares |x Composés | ||
| 650 | |a Chimie des états excités | ||
| 776 | 0 | |t Transition Metal and Rare Earth Compounds |b Texte imprimé |z 9783540679769 | |
| 776 | 0 | |t Transition Metal and Rare Earth Compounds |b Texte imprimé |z 9783642087578 | |
| 776 | 0 | |t Transition Metal and Rare Earth Compounds |b Texte imprimé |z 9783662146910 | |
| 856 | 4 | |q PDF |u https://doi.org/10.1007/3-540-44474-2 |z Accès sur la plateforme de l'éditeur | |
| 856 | 4 | |u https://revue-sommaire.istex.fr/ark:/67375/8Q1-9GQW0524-F |z Accès sur la plateforme Istex | |
| 856 | 4 | |5 452349901:750670886 |u https://ezproxy.univ-orleans.fr/login?url=https://doi.org/10.1007/3-540-44474-2 |z Accès Université d'Orléans | |
| 856 | 4 | |5 180339901:754019748 |u https://ezproxy.insa-cvl.fr/login?qurl=https://doi.org/10.1007/3-540-44474-2 |z Accès INSA CVL | |
| 997 | |0 969729 |1 Livre numérique |a Ressource numérique |b INSA |b ENSA |c 0/Bibliothèque numérique/ |c 1/Bibliothèque numérique/Autre ressource numérique/ | ||

