Visualization of hydrogen-bond dynamics : water-based model systems on a Cu(110) surface
The hydrogen bond represents an important interaction between molecules, and the dynamics of hydrogen bonds in water create an ever-present question associated with the process of chemical and biological reactions. In spite of numerous studies, the process remains poorly understood at the microscopi...
Uloženo v:
| Hlavní autor: | |
|---|---|
| Médium: | Livre numérique |
| Jazyk: | Anglais |
| Vydáno: |
Tokyo :
Springer Japan
[20..].
Cham : Springer Nature |
| Vydání: | 1st ed. 2012. |
| Edice: | Springer Theses, Recognizing Outstanding Ph.D. Research
125 |
| On-line přístup: | Accès sur la plateforme de l'éditeur Accès sur la plateforme Istex Accès Université d'Orléans Accès INSA CVL |
| Poznámka: |
Archives Springer e-books (Licence nationale) Archives Springer e-books (Licence nationale) |
| Autres localisations: | Voir dans le Sudoc |
| Edition sous un autre format: | • Visualization of Hydrogen-Bond Dynamics, Texte imprimé, 9784431541554 • Visualization of Hydrogen-Bond Dynamics, Texte imprimé, 9784431541578 • Visualization of Hydrogen-Bond Dynamics, Texte imprimé, 9784431547358 • Visualization of Hydrogen-Bond Dynamics, Texte imprimé, 9784431541554 |
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| 100 | 1 | |a Kumagai, Takashi, |d 1967-...., |c mathématicien. | |
| 245 | 1 | 0 | |a Visualization of hydrogen-bond dynamics : |b water-based model systems on a Cu(110) surface |c by Takashi Kumagai. |
| 250 | |a 1st ed. 2012. | ||
| 260 | |a Tokyo : |b Springer Japan. | ||
| 260 | |a Cham : |b Springer Nature, |c [20..]. | ||
| 490 | 0 | |a Springer Theses, Recognizing Outstanding Ph.D. Research |v 125 |x 2190-5061 | |
| 500 | |a Archives Springer e-books (Licence nationale) | ||
| 500 | |a Archives Springer e-books (Licence nationale) | ||
| 505 | 1 | |a Introduction Principles and Techniques Experiments Water Monomer: Structure and Diffusion of a Single Water Molecule Water Dimer: Direct Observation of Hydrogen-Bond Exchange Water Clusters: Formation of One-Dimensional Water Clusters Hydroxyl Group: Tunneling Dynamics of Hydrogen Atom Hydroxyl Dimer: Non-linear I V Characteristics in an STM Junction Water-Hydroxyl Complexes: Direct Observation of a Symmetric Hydrogen Bond One-Dimensional Water-Hydroxyl Chain Complexes: Hydrogen-Atom Relay Reactions in Real Space Conclusions | |
| 506 | |a Accès en ligne pour les établissements français bénéficiaires des licences nationales | ||
| 506 | |a Accès soumis à abonnement pour tout autre établissement | ||
| 506 | |a Conditions particulières de réutilisation pour les bénéficiaires des licences nationales. https://www.licencesnationales.fr/springer-nature-ebooks-contrat-licence-ln-2017 | ||
| 520 | |a The hydrogen bond represents an important interaction between molecules, and the dynamics of hydrogen bonds in water create an ever-present question associated with the process of chemical and biological reactions. In spite of numerous studies, the process remains poorly understood at the microscopic level because hydrogen-bond dynamics, such as bond rearrangements and hydrogen/proton transfer reactions, are extremely difficult to probe. Those studies have been carried out by means of spectroscopic methods where the signal stems from the ensemble of a system and the hydrogen-bond dynamics were inferred indirectly. This book addresses the direct imaging of hydrogen-bond dynamics within water-based model systems assembled on a metal surface, using a scanning tunneling microscope (STM). The dynamics of individual hydrogen bonds in water clusters, hydroxyl clusters, and water-hydroxyl complexes are investigated in conjunction with density functional theory. In these model systems, quantum dynamics of hydrogen bonds, such as tunneling and zero-point nuclear motion, are observed in real space. Most notably, hydrogen atom relay reactions, which are frequently invoked across many fields of chemistry, are visualized and controlled by STM. This work presents a means of studying hydrogen-bond dynamics at the single-molecule level, providing an important contribution to wide fields beyond surface chemistry | ||
| 776 | 0 | |t Visualization of Hydrogen-Bond Dynamics |b Texte imprimé |z 9784431541554 | |
| 776 | 0 | |t Visualization of Hydrogen-Bond Dynamics |b Texte imprimé |z 9784431541578 | |
| 776 | 0 | |t Visualization of Hydrogen-Bond Dynamics |b Texte imprimé |z 9784431547358 | |
| 776 | 0 | |t Visualization of Hydrogen-Bond Dynamics |b Texte imprimé |z 9784431541554 | |
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