Molecular conformation and organic photochemistry : time-resolved photoionization studies

Rasmus Brogaard's thesis digs into the fundamental issue of how the shape of a molecules relates to its photochemical reactivity. This relation is drastically different from that of ground-state chemistry, since lifetimes of excited states are often comparable to or even shorter than the time s...

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Xehetasun bibliografikoak
Egile nagusia: Brogaard, Rasmus Y., 19..-
Formatua: Livre numérique
Hizkuntza:Anglais
Argitaratua: Berlin, Heidelberg : Springer Berlin Heidelberg [20..].
Cham : Springer Nature
Edizioa:1st ed. 2012.
Saila:Springer Theses, Recognizing Outstanding Ph.D. Research
Sarrera elektronikoa:Accès sur la plateforme de l'éditeur
Accès sur la plateforme Istex
Accès Université d'Orléans
Accès INSA CVL
Oharra: Archives Springer e-books (Licence nationale)
Archives Springer e-books (Licence nationale)
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Edition sous un autre format:• Molecular Conformation and Organic Photochemistry, Texte imprimé, 9783642293801
• Molecular Conformation and Organic Photochemistry, Texte imprimé, 9783642293825
• Molecular Conformation and Organic Photochemistry, Texte imprimé, 9783642426742
• Molecular Conformation and Organic Photochemistry, Texte imprimé, 9783642293801
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245 1 0 |a Molecular conformation and organic photochemistry :  |b time-resolved photoionization studies   |c by Rasmus Y. Brogaard. 
250 |a 1st ed. 2012. 
260 |a Berlin, Heidelberg :  |b Springer Berlin Heidelberg. 
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505 1 |a Aspects and investigation of photochemical dynamics A time-resolved probing method: photoionization Simulation of time-resolved photoionization signals Simulation: the Norrish type-I reaction in acetone Experimental setups Paracyclophanes I: [2+2]cycloaddition of ethylenes Paracyclophanes II: The Paternò-Büchi reaction Probing structural dynamics by interaction between chromophores 
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520 |a Rasmus Brogaard's thesis digs into the fundamental issue of how the shape of a molecules relates to its photochemical reactivity. This relation is drastically different from that of ground-state chemistry, since lifetimes of excited states are often comparable to or even shorter than the time scales of conformational changes. Combining theoretical and experimental efforts in femto-second time-resolved photoionization Rasmus Brogaard finds that a requirement for an efficient photochemical reaction is the prearrangement of the constituents in a reactive conformation. Furthermore, he is able to show that by exploiting a strong ionic interaction between two chromophores, a coherent molecular motion can be induced and probed in real-time. This way of using bichromophoric interactions provides a promising strategy for future research on conformational dynamics 
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776 0 |t Molecular Conformation and Organic Photochemistry  |b Texte imprimé  |z 9783642293801 
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