Hierarchical bottom-up methodology for integrating dynamic ethynylhelicene oligomers : synthesis, double helix formation, and the higher assembly formation

In biological systems, molecules hierarchically form ordered assemblies and macroscopic substances, as exemplified by the assembly of proteins. The development of such systems using oligomeric macromolecules obtained by organic synthesis can provide insights into biological phenomena and will lead t...

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Hovedforfatter: Saito, Nozomi
Format: Livre numérique
Sprog:Anglais
Udgivet: Tokyo : Springer Japan [20..].
Cham : Springer Nature
Udgivelse:1st ed. 2013.
Serier:Springer Theses, Recognizing Outstanding Ph.D. Research
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Edition sous un autre format:• Hierarchical Bottom-Up Methodology for Integrating Dynamic Ethynylhelicene Oligomers, Texte imprimé, 9784431545132
• Hierarchical Bottom-Up Methodology for Integrating Dynamic Ethynylhelicene Oligomers, Texte imprimé, 9784431545156
• Hierarchical Bottom-Up Methodology for Integrating Dynamic Ethynylhelicene Oligomers, Texte imprimé, 9784431545132
• Hierarchical Bottom-Up Methodology for Integrating Dynamic Ethynylhelicene Oligomers, Texte imprimé, 9784431563716
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245 1 0 |a Hierarchical bottom-up methodology for integrating dynamic ethynylhelicene oligomers :  |b synthesis, double helix formation, and the higher assembly formation   |c by Nozomi Saito. 
250 |a 1st ed. 2013. 
260 |a Tokyo :  |b Springer Japan. 
260 |a Cham :  |b Springer Nature,  |c [20..]. 
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505 1 |a From the contents: Introduction: Hierarchical Bottom-Up Methodology for Integrating Synthesis of Ethynylhelicene Oligomers Homo-Double Helix Formation of Ethynylhelicene Oligomers Possessing Various Side Chains Hetero-Double Helix Formation of Pseudoenantiomeric Ethynylhelicene Oligomers.-Higher Assembly Formation of Pseudoenantiomeric Ethynylhelicene Oligomers Conclusions Experimental Section 
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506 |a Conditions particulières de réutilisation pour les bénéficiaires des licences nationales. https://www.licencesnationales.fr/springer-nature-ebooks-contrat-licence-ln-2017 
520 |a In biological systems, molecules hierarchically form ordered assemblies and macroscopic substances, as exemplified by the assembly of proteins. The development of such systems using oligomeric macromolecules obtained by organic synthesis can provide insights into biological phenomena and will lead to the creation of new materials. In this regard, synthetic double helix molecules are attractive subjects of study because they have an important structural motif  that appears widely in nature and can exhibit dynamic structural change. This thesis describes an unprecedented bottom-up approach using synthetic ethynylhelicene oligomers, which form dynamic double helices in organic media. Oligomer synthesis, homo- and hetero-double helix formation, and higher assembly formation due to intercomplex interactions are documented. The hierarchical assembly formation is a cogent reminder of the assembly of biological proteins that create living creatures. Also notable here is the demonstration of a methodology of providing diverse hetero-double helices and their higher assemblies by changing the combination of oligomers, which can be another advantage of this synthetic system 
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