Three-dimensional free-radical polymerization : cross-linked and hyper-branched polymers
At present, three-dimensional free-radical polymerization (TFRP) is a special ?eld of radical polymerization. TFRP is characterized by speci?c kinetic regularities and mechanisms of processes for the formation of cross-linked or hyper-branched po- mers, and they are different from the kinetics and m...
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| Auteurs principaux: | , |
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| Format: | Livre numérique |
| Sprog: | Anglais |
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Berlin, Heidelberg :
Springer Berlin Heidelberg : Springer e-books
[20..].
Cham : Springer Nature |
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Archives Springer e-books (Licence nationale) Archives Springer e-books (Licence nationale) |
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| Edition sous un autre format: | • Three-dimensional free-radical polymerization, cross-linked and hyper-branched polymers, Gennady V. Korolev, Michael M. Mogilevich, Berlin, Springer, 2009, 1 vol. (VIII-270 p.), 978-3-540-87566-6 |
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| 100 | 1 | |a Korolev, Gennady Vladimirovich. | |
| 245 | 1 | 0 | |a Three-dimensional free-radical polymerization : |b cross-linked and hyper-branched polymers |c by Gennady V. Korolev, Michael M. Mogilevich. |
| 260 | |a Berlin, Heidelberg : |b Springer Berlin Heidelberg : |b Springer e-books. | ||
| 260 | |a Cham : |b Springer Nature, |c [20..]. | ||
| 500 | |a Archives Springer e-books (Licence nationale) | ||
| 500 | |a Archives Springer e-books (Licence nationale) | ||
| 505 | 1 | |a Three-Dimensional Free-Radical Polymerization. Cross-Linked Polymers Microheterogeneous Mechanism of Three-Dimensional Free-Radical Polymerization Kinetic Features of Three-Dimensional Free-Radical Polymerization Living Chain Three-Dimensional Radical Polymerization Kinetic Features of Three-Dimensional Free-Radical Copolymerization Critical Conversion (Gel Point) in Three-Dimensional Free-Radical Polymerization Properties of Cross-Linked Polymers and Copolymers Three-Dimensional Free-Radical Polymerization. Hyper-Branched Polymers Synthesis of Hyper-Branched Polymers Properties and Application of Hyper-Branched Polymers Methods for Studying Three-Dimensional Free-Radical Polymerization and Cross-Linked Polymers | |
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| 506 | |a Conditions particulières de réutilisation pour les bénéficiaires des licences nationales. https://www.licencesnationales.fr/springer-nature-ebooks-contrat-licence-ln-2017 | ||
| 520 | |a At present, three-dimensional free-radical polymerization (TFRP) is a special ?eld of radical polymerization. TFRP is characterized by speci?c kinetic regularities and mechanisms of processes for the formation of cross-linked or hyper-branched po- mers, and they are different from the kinetics and mechanism of classical radical polymerization. The fundamental studies of kinetics and mechanism of TFRP with formation of cross-linked polymers have been carried out in three stages. The ?rst stage lasted from 1960 until 1983, and the main mechanisms of TFRP of oligo(acrylates) were established during this stage [1 3]. Condensation telomerization, being a universal oligo(acrylate) synthesis procedure, allows us to vary certain molecular parameters, such as length and ?exibility of oligomeric blocks, number and type of reactive groups (methacrylic or acrylic groups), and chemical nature of atomic groups of an oligomeric block, which represent the centers of strong intermolecular interactions. For this reason, oligo(acrylates) were very convenient compounds for establi- ing the main kinetic regularities of TFRP and regularities of formation of polymer three-dimensional cross-linkedstructures,according totheso-calledmicrohetero- neous mechanism (G.V. Korolev, 1977), at the topological and morphological levels | ||
| 700 | 1 | |a Mogilevich, Mikhail Markovich. |4 aut | |
| 776 | 0 | |0 132843056 |t Three-dimensional free-radical polymerization |o cross-linked and hyper-branched polymers |f Gennady V. Korolev, Michael M. Mogilevich |c Berlin |n Springer |d 2009 |p 1 vol. (VIII-270 p.) |z 978-3-540-87566-6 | |
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| 856 | 4 | |5 180339901:75086771X |u https://ezproxy.insa-cvl.fr/login?qurl=https://doi.org/10.1007/978-3-540-87567-3 |z Accès INSA CVL | |
| 997 | |0 941198 |1 Livre numérique |a Ressource numérique |b INSA |b ENSA |c 0/Bibliothèque numérique/ |c 1/Bibliothèque numérique/Autre ressource numérique/ | ||

