Directed Metallation
Directed metalation is recognized as one of the most useful methodologies for the regio- and stereoselective generation of organometallic species, the generation of which necessarily leads to the selective formation of organic products. Cyclometalation using Li, Mn, and Pd, and directed hydrometalat...
Kaydedildi:
| Yazar: | |
|---|---|
| Materyal Türü: | Livre numérique |
| Dil: | Anglais |
| Baskı/Yayın Bilgisi: |
Berlin, Heidelberg :
Springer Berlin Heidelberg
[20..].
Cham : Springer Nature |
| Edisyon: | 1st ed. 2007. |
| Seri Bilgileri: | Topics in Organometallic Chemistry
24 |
| Online Erişim: | Accès sur la plateforme de l'éditeur Accès sur la plateforme Istex Accès Université d'Orléans Accès INSA CVL |
| Not: |
Archives Springer e-books (Licence nationale) Archives Springer e-books (Licence nationale) |
| Autres localisations: | Voir dans le Sudoc |
| Edition sous un autre format: | • Directed Metallation, Texte imprimé, 9783540758082 • Directed Metallation, Texte imprimé, 9783540845195 • Directed Metallation, Texte imprimé, 9783642094934 |
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| 100 | 1 | |a Chatani, Naoto. | |
| 245 | 1 | 0 | |a Directed Metallation |c edited by Naoto Chatani. |
| 250 | |a 1st ed. 2007. | ||
| 260 | |a Berlin, Heidelberg : |b Springer Berlin Heidelberg. | ||
| 260 | |a Cham : |b Springer Nature, |c [20..]. | ||
| 490 | 0 | |a Topics in Organometallic Chemistry |v 24 |x 1616-8534 | |
| 500 | |a Archives Springer e-books (Licence nationale) | ||
| 500 | |a Archives Springer e-books (Licence nationale) | ||
| 505 | 1 | |a Catalytic Addition of C? ?H Bonds to C? ?C Multiple Bonds Chelation-Assisted Arylation via C H Bond Cleavage Catalytic Arylation and Vinylation Reactions Directed by Anionic Oxygen Functions via Cleavage of C? ?H and C? ?C Bonds Chelate-Directed Oxidative Functionalization of Carbon Hydrogen Bonds: Synthetic Applications and Mechanistic Insights Directed C? ?C Bond Activation by Transition Metal Complexes Directed Rhodium-Catalyzed Hydroformylation of Alkenes Directed Mizoroki Heck Reactions | |
| 506 | |a Accès en ligne pour les établissements français bénéficiaires des licences nationales | ||
| 506 | |a Accès soumis à abonnement pour tout autre établissement | ||
| 506 | |a Conditions particulières de réutilisation pour les bénéficiaires des licences nationales. https://www.licencesnationales.fr/springer-nature-ebooks-contrat-licence-ln-2017 | ||
| 520 | |a Directed metalation is recognized as one of the most useful methodologies for the regio- and stereoselective generation of organometallic species, the generation of which necessarily leads to the selective formation of organic products. Cyclometalation using Li, Mn, and Pd, and directed hydrometalation and carbometalation using Al and Zn, have been utilized for regio- and/or stereoselective synthesis for decades. Recently, a new chelation-assisted methodology has been developed not only for controlling regio- and stereoselectivity of reactions, but also for accelerating reactions. In particular, chelation-methodology has been utilized as a new activation method, in which a carbon-metal bond is generated directly from a C-H bond; a reaction rarely achieved using conventional methods. A wide variety of catalytic functionalization reactions of C-H bonds by the utilization of a chelation, have been developed recently and are comprehensively discussed in this book by leading experts. In addition, new approaches to directed hydrometalation and directed carbometalation as a key step are also discussed. A unique stereo- and regioselective hydroformylation has been developed through the utilization of directed hydrometalation. The regioselective Mizoroki-Heck reaction is another example in which directed carbometalation can be used to achieve a high regioselectivity. These examples emphasize how these innovative methodologies are contributing to different fields of chemistry | ||
| 776 | 0 | |t Directed Metallation |b Texte imprimé |z 9783540758082 | |
| 776 | 0 | |t Directed Metallation |b Texte imprimé |z 9783540845195 | |
| 776 | 0 | |t Directed Metallation |b Texte imprimé |z 9783642094934 | |
| 856 | 4 | |q PDF |u https://doi.org/10.1007/978-3-540-75809-9 |z Accès sur la plateforme de l'éditeur | |
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| 856 | 4 | |5 452349901:747872600 |u https://ezproxy.univ-orleans.fr/login?url=https://dx.doi.org/10.1007/978-3-540-75809-9 |z Accès Université d'Orléans | |
| 856 | 4 | |5 180339901:750884886 |u https://ezproxy.insa-cvl.fr/login?qurl=https://dx.doi.org/10.1007/978-3-540-75809-9 |z Accès INSA CVL | |
| 997 | |0 940029 |1 Livre numérique |a Ressource numérique |b INSA |b ENSA |c 0/Bibliothèque numérique/ |c 1/Bibliothèque numérique/Autre ressource numérique/ | ||