Halogen Bonding : Fundamentals and Applications

Halogen atoms in organiccompounds can typically be foundat the periphery of molecules. For this reason, they are ideally positioned to be involved in intermolecular interactions. Indeed, halogen atoms are frequently involved in awide varietyofnon-covalent interactions whichcanberemarkably different...

Disgrifiad llawn

Wedi'i Gadw mewn:
Manylion Llyfryddiaeth
Prif Awdur: Metrangolo, Pierangelo
Awduron Eraill: Resnati, Giuseppe, 19..- (Golygydd)
Fformat: Livre numérique
Iaith:Anglais
Cyhoeddwyd: Berlin, Heidelberg : Springer Berlin Heidelberg [20..].
Cham : Springer Nature
Rhifyn:1st ed. 2008.
Cyfres:Structure and Bonding 301
Pynciau:
Mynediad Ar-lein:Accès sur la plateforme de l'éditeur
Accès sur la plateforme Istex
Accès Université d'Orléans
Accès INSA CVL
Nodyn: Archives Springer e-books (Licence nationale)
Archives Springer e-books (Licence nationale)
Autres localisations: Voir dans le Sudoc
Variante du titre:With contributions by numerous experts
Edition sous un autre format:• Halogen bonding, fundamentals and applications, Volume Editors P. Metrangolo, G. Resnati, Berlin, Springer, 2008, 1 vol. (221 p.), Structure and bonding, 978-3-540-74329-3
• Halogen Bonding, Texte imprimé, 9783642093708
• Halogen Bonding, Texte imprimé, 9783540842521
• Halogen bonding, fundamentals and applications, Volume Editors P. Metrangolo, G. Resnati, Berlin, Springer, 2008, 1 vol. (221 p.), Structure and bonding, 978-3-540-74329-3
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245 1 0 |a Halogen Bonding :  |b Fundamentals and Applications   |c edited by P. Metrangolo, G. Resnati. 
250 |a 1st ed. 2008. 
260 |a Berlin, Heidelberg :  |b Springer Berlin Heidelberg. 
260 |a Cham :  |b Springer Nature,  |c [20..]. 
490 0 |a Structure and Bonding  |v 301  |x 1616-8550 
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500 |a Archives Springer e-books (Licence nationale) 
505 1 |a Theoretical Characterization of the Trends in Halogen Bonding The Interaction of Dihalogens and Hydrogen Halides with Lewis Bases in the Gas Phase: An Experimental Comparison of the Halogen Bond and the Hydrogen Bond Halogen Bonding with Dihalogens and Interhalogens Halogen Bonding in Crystal Engineering X-ray Structures and Electronic Spectra of the ?-Halogen Complexes between Halogen Donors and Acceptors with ?-Receptors Halogen-bonded Liquid Crystals Halogen Bonding in Conducting or Magnetic Molecular Materials 
506 |a Accès en ligne pour les établissements français bénéficiaires des licences nationales 
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520 |a Halogen atoms in organiccompounds can typically be foundat the periphery of molecules. For this reason, they are ideally positioned to be involved in intermolecular interactions. Indeed, halogen atoms are frequently involved in awide varietyofnon-covalent interactions whichcanberemarkably different regarding their energetic and geometric features. Theoretical studies predict thattheelectrondensitydistributionaroundhalogenatomsformsanellipsoid elongated in the direction perpendicular to the covalent bond axis. A clear trend ofincreasing electropositive potential develops alongthe covalent bond axisuponincreasingthepolarizabilityandatomicmassofthehalogen.Exp- imentalresultscon?rmthisanisotropicdistributionandprovetheamphoteric characterofhalogens.Thiscanproduceinteractionsinadirectionperpend- ular to the covalent bond axis when the halogen is the electron donor (Lewis base), and along the axis when the halogen is the electron acceptor (Lewis acid). This book focuses on the interactions wherein halogens work as el- trophilicspecies and interact with electron rich sites (namely, electronegative partners).Ofthenumerousnon-covalentinteractionsinvolvinghalogens,this particular subset istypically referredto ashalogen bonding.The bookbegins byintroducingtheoreticalcalculationsonthecharacteristicsofhalogenbo- ing (A. Karpfen), then focuses on the adducts wherein the electron donor is a lone pair possessing species (n donor). The complexes formed by halogens andinterhalogensinthegas(A.Legon)andsolidphase(W. T.Penningtonetal.) arepresentedandtheroleofhalocarbonsinhalogenbonding-basedcrystal- gineeringisdiscussed(P.Metrangolo,G.Resnatietal.).Achapterexploringthe complexesinwhichhalogenatomsinteractwith? electrondonors(J.K.Kochi etal.)concludesthepartofthebookthatdealswiththegeneralitiesofhalogen bonding.Incontrast,thelasttwochaptersofthisbookdiscusshalogenbonded adducts endowed with useful applicative properties. Among the many novel applications of halogen bonding, liquid crystals(D. Bruce) and conducting or magnetic materials (M. Fourmigue)are discussed as prototypicalexamples 
650 |a Chimie 
650 |a Chimie physique et théorique 
650 |a Chimie analytique 
650 |a Halogènes 
650 |a Chimie inorganique 
650 |a Associations moléculaires 
700 1 |a Resnati, Giuseppe,  |d 19..-  |4 edt 
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776 0 |t Halogen Bonding  |b Texte imprimé  |z 9783642093708 
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