Functional Materials and Biomaterials.

Hyperbranched polymers have emerged as a new class of macromolecules that show architectural beauty and multifaceted functionality of d- drimers while enjoying the ease of being prepared by simple, sing- step reaction procedures. A number of strategies have been developed for the synthesis of hyperb...

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Diğer Yazarlar: Abe, Akihiro (Yayın yönetmeni), Lucas, Patrice, chimiste (Yayın yönetmeni), Robin, Jean-Jacques, 19..-...., chimiste (Yayın yönetmeni), Tang, Ben Zhong, 19..- (Yayın yönetmeni)
Materyal Türü: Livre numérique
Dil:Anglais
Baskı/Yayın Bilgisi: Berlin, Heidelberg : Springer Berlin Heidelberg [20..].
Cham : Springer Nature
Edisyon:1st ed. 2007.
Seri Bilgileri:Advances in Polymer Science 209
Konular:
Online Erişim:Accès sur la plateforme de l'éditeur
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Not: Archives Springer e-books (Licence nationale)
Archives Springer e-books (Licence nationale)
Autres localisations: Voir dans le Sudoc
Variante du titre:With contributions by numerous experts
Edition sous un autre format:• Functional materials and biomaterials, with contributions by X. Dong Liu ... [et al.], Berlin, Springer, 2007, 1 vol. (VI- 237 p.), Advances in polymer science, 3-540-71508-8
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505 1 |a M. Haeussler, B.Z. Tang: Functional Hyperbranched Macromolecules Constructed from Acetylenic Triple-Bond Building Blocks A.R. Esker, C. Kim and;H. Yu: Polymer Monolayer Dynamics P. Lucas, J.-J. Robin: Silicone Based Polymer Blends: An Overview of the Materials and Processes X.D. Liu, M. Yamada, M. Matsunaga and N. Nishi: Functional Materials Derived from DNA D.-A. Wang: Engineering Blood-Contact Biomaterials by "H-Bond Grafting" Surface Modification 
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520 |a Hyperbranched polymers have emerged as a new class of macromolecules that show architectural beauty and multifaceted functionality of d- drimers while enjoying the ease of being prepared by simple, sing- step reaction procedures. A number of strategies have been developed for the synthesis of hyperbranched polymers. The commonly adopted - proach is self-condensation polymerization of AB -type monomers with x x?2 where A and B are mutually reactive functional groups, dating back to the theoretical work of Flory in the early 1950s [1]. Because of the limited commercial availability and dif?cult synthetic access to multifu- tional monomers bearing multiple, mutually reactive groups, alternative approaches suchas copolymerizations ofA monomers with B comonomers 2 x (x?3) have been developed [2 7]. Other polymerization reactions including self-condensing vinyl polymerizations initiated by cationic [8] and radical catalysts [9,10] and ring-opening multibranching polymerizations [11 15] have been explored, mainly for the synthesis of non-conjugated hyp- branched polymers [16 18]. Hyperbranched macromolecules have been constructed from various functional groups, among which, carbon-carbon triple-bond functionality uniquely stands out because it offers ready access to hyperbranched conju- tive macromolecules. Being unsaturated, it accommodates various addition reactions. In comparison to vinyl and alkyl protons, the acetylenic proton is most acidic (pK = 26; cf. , pK =45forethyleneandpK = 62 for ethane), a a a thus enabling facile substitution and coupling reactions 
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