Hydroboration and Organic Synthesis : 9-Borabicyclo [3.3.1] nonane (9-BBN)
9-Borabicyclo [3.3.1]nonane, a commercially available reagent, is the most versatile hydroborating reagent to synthesize organoboranes (B-R-9-BBN). The reagent exhibits remarkable regio-, chemo-, and stereoselectivity during hydroboration reactions. The organoboranes can be converted to C-H, C-O, C-...
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| Médium: | Livre numérique |
| Jazyk: | Anglais |
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Berlin, Heidelberg :
Springer Berlin Heidelberg : Springer e-books
[20..].
Cham : Springer Nature |
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Archives Springer e-books (Licence nationale) Archives Springer e-books (Licence nationale) |
| Autres localisations: | Voir dans le Sudoc |
| Edition sous un autre format: | • Hydroboration and organic synthesis, 9-borabicyclo[3.3.1]nonane (9-BBN), Ranjit S. Dhillon, Berlin, Springer-Verlag, 2007, 1 vol. (XIII-586 p), 978-3-540-49075-3 |
Obsah:
- General Remarks Preparation and Properties Kinetic Studies Hydroboration Synthesis of Alcohols Synthesis of Aldehydes and Ketones Synthesis of Carboxylic Acids Synthesis of Esters Synthesis of Nitriles Synthesis of (E)-?,?-Unsaturated Amides Synthesis of Amines Synthesis of Halides Synthesis of Dialkylsulfides Synthesis of Thiophene Oligomers Synthesis of Cyclopropanes and Cyclobutanes Synthesis of Borinanes Synthesis and Transformations of Butterflyboranes: cis-Bicyclo[3.3.0]oct-1-yldialkylboranes Synthesis of ?-Bromoboranes Synthesis of Borinates Synthesis and Transformation of Polymers Synthesis of Alkali Metal 9-Boratabicyclo[3.3.1] nonane (Li, K, and Na 9-BBNH) Synthesis of B-R-9-BBN Not Available via Hydroboration Synthesis of Unsaturated Compounds Reduction Asymmetric Reduction Cleavage of Ethers trans-Metalation Separation of Isomers Diels-Alder Reaction Suzuki Reaction Miscellaneous Reactions