Hydroboration and Organic Synthesis : 9-Borabicyclo [3.3.1] nonane (9-BBN)

9-Borabicyclo [3.3.1]nonane, a commercially available reagent, is the most versatile hydroborating reagent to synthesize organoboranes (B-R-9-BBN). The reagent exhibits remarkable regio-, chemo-, and stereoselectivity during hydroboration reactions. The organoboranes can be converted to C-H, C-O, C-...

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Huvudupphovsman: Dhillon, Ranjit S.
Materialtyp: Livre numérique
Språk:Anglais
Publicerad: Berlin, Heidelberg : Springer Berlin Heidelberg : Springer e-books [20..].
Cham : Springer Nature
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Anmärkning: Archives Springer e-books (Licence nationale)
Archives Springer e-books (Licence nationale)
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Edition sous un autre format:• Hydroboration and organic synthesis, 9-borabicyclo[3.3.1]nonane (9-BBN), Ranjit S. Dhillon, Berlin, Springer-Verlag, 2007, 1 vol. (XIII-586 p), 978-3-540-49075-3
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505 1 |a General Remarks Preparation and Properties Kinetic Studies Hydroboration Synthesis of Alcohols Synthesis of Aldehydes and Ketones Synthesis of Carboxylic Acids Synthesis of Esters Synthesis of Nitriles Synthesis of (E)-?,?-Unsaturated Amides Synthesis of Amines Synthesis of Halides Synthesis of Dialkylsulfides Synthesis of Thiophene Oligomers Synthesis of Cyclopropanes and Cyclobutanes Synthesis of Borinanes Synthesis and Transformations of Butterflyboranes: cis-Bicyclo[3.3.0]oct-1-yldialkylboranes Synthesis of ?-Bromoboranes Synthesis of Borinates Synthesis and Transformation of Polymers Synthesis of Alkali Metal 9-Boratabicyclo[3.3.1] nonane (Li, K, and Na 9-BBNH) Synthesis of B-R-9-BBN Not Available via Hydroboration Synthesis of Unsaturated Compounds Reduction Asymmetric Reduction Cleavage of Ethers trans-Metalation Separation of Isomers Diels-Alder Reaction Suzuki Reaction Miscellaneous Reactions 
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520 |a 9-Borabicyclo [3.3.1]nonane, a commercially available reagent, is the most versatile hydroborating reagent to synthesize organoboranes (B-R-9-BBN). The reagent exhibits remarkable regio-, chemo-, and stereoselectivity during hydroboration reactions. The organoboranes can be converted to C-H, C-O, C-N, C-S, C-halogen, C-metal and above all C-C bonds. In addition, the suitable substituted / unsaturated R of B-R-9-BBN can be utilized to produce dienes, enynes, allenes etc. with defined stereochemistry. 9-BBN s derivatives have been elegantly used for the asymmetric reduction of ketone moiety. Diels-Alder and Suzuki reactions have expanded the utility of 9-BBN for the synthesis of a variety of organic compounds required for industry. Consequently, this vast field in the form of a book will be helpful to synthetic organic chemists for easy access to literature, required for chemical transformations 
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