Magnetic Functions Beyond the Spin-Hamiltonian
Using the spin-Hamiltonian formalism the magnetic parameters are introduced through the components of the Lambda-tensor involving only the matrix elements of the angular momentum operator. The energy levels for a variety of spins are generated and the modeling of the magnetization, the magnetic susc...
Gardado en:
| Autor Principal: | |
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| Outros autores: | |
| Formato: | Livre numérique |
| Idioma: | Anglais |
| Publicado: |
Berlin, Heidelberg :
Springer Berlin Heidelberg
[20..].
Cham : Springer Nature |
| Edición: | 1st ed. 2006. |
| Series: | Structure and Bonding
117 |
| Sujets: | |
| Acceso en liña: | Accès sur la plateforme de l'éditeur Accès sur la plateforme Istex Accès Université d'Orléans Accès INSA CVL |
| Nota: |
Archives Springer e-books (Licence nationale) Archives Springer e-books (Licence nationale) |
| Autres localisations: | Voir dans le Sudoc |
| Edition sous un autre format: | • Magnetic functions beyond the spin-Hamiltonian, Volume Editor: D.M.P. Mingos, Berlin, Springer, 2006, 1 vol. (276 p.), Structure and bonding, 3-540-26079-X • Magnetic Functions Beyond the Spin-Hamiltonian, Texte imprimé, 9783642065439 • Magnetic Functions Beyond the Spin-Hamiltonian, Texte imprimé, 9783540811206 • Magnetic functions beyond the spin-Hamiltonian, Volume Editor: D.M.P. Mingos, Berlin, Springer, 2006, 1 vol. (276 p.), Structure and bonding, 3-540-26079-X |
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| 100 | 1 | |a Mingos, David Michael P. | |
| 245 | 1 | 0 | |a Magnetic Functions Beyond the Spin-Hamiltonian |c edited by D. M. P. Mingos. |
| 250 | |a 1st ed. 2006. | ||
| 260 | |a Berlin, Heidelberg : |b Springer Berlin Heidelberg. | ||
| 260 | |a Cham : |b Springer Nature, |c [20..]. | ||
| 490 | 0 | |a Structure and Bonding |v 117 |x 1616-8550 | |
| 500 | |a Archives Springer e-books (Licence nationale) | ||
| 500 | |a Archives Springer e-books (Licence nationale) | ||
| 505 | 1 | |a R. Boca: Magnetic Parameters and Magnetic Functions in Mononuclear Complexes Beyond the Spin-Hamiltonian Formalism: Introduction Energy Levels of Multi-Term Systems Modeling the Magnetic Parameters Calculations of Energy Levels and Magnetic Parameters Empirical Magnetic Parameters Conclusions References Appendix A: Spectroscopic Constants, Coefficients and Matrix Elements Appendix B: Elements of the Irreducible Tensor Approach Appendix C: Classification of Crystal-Field Terms and Multiplets Appendix D: Calculated Energy Levels and Magnetic Parameters | |
| 506 | |a Accès en ligne pour les établissements français bénéficiaires des licences nationales | ||
| 506 | |a Accès soumis à abonnement pour tout autre établissement | ||
| 506 | |a Conditions particulières de réutilisation pour les bénéficiaires des licences nationales. https://www.licencesnationales.fr/springer-nature-ebooks-contrat-licence-ln-2017 | ||
| 520 | |a Using the spin-Hamiltonian formalism the magnetic parameters are introduced through the components of the Lambda-tensor involving only the matrix elements of the angular momentum operator. The energy levels for a variety of spins are generated and the modeling of the magnetization, the magnetic susceptibility and the heat capacity is done. Theoretical formulae necessary in performing the energy level calculations for a multi-term system are prepared with the help of the irreducible tensor operator approach. The goal of the programming lies in the fact that the entire relevant matrix elements (electron repulsion, crystal field, spin-orbit interaction, orbital-Zeeman, and spin-Zeeman operators) are evaluated in the basis set of free-atom terms. The modeling of the zero-field splitting is done at three levels of sophistication. The spin-Hamiltonian formalism offers simple formulae for the magnetic parameters by evaluating the matrix elements of the angular momentum operator in the basis set of the crystal-field terms. The magnetic functions for dn complexes are modeled for a wide range of the crystal-field strengths | ||
| 650 | |a Magnétisme | ||
| 650 | |a Propriétés magnétiques | ||
| 650 | |a Chimie | ||
| 650 | |a Susceptibilité magnétique | ||
| 650 | |a Chimie physique et théorique | ||
| 650 | |a Métaux de transition |x Complexes | ||
| 650 | |a Chimie inorganique | ||
| 700 | 1 | |a Mingos, David Michael P., |d 1944- |4 edt | |
| 776 | 0 | |0 097673226 |t Magnetic functions beyond the spin-Hamiltonian |f Volume Editor: D.M.P. Mingos |c Berlin |n Springer |d 2006 |p 1 vol. (276 p.) |s Structure and bonding |z 3-540-26079-X | |
| 776 | 0 | |t Magnetic Functions Beyond the Spin-Hamiltonian |b Texte imprimé |z 9783642065439 | |
| 776 | 0 | |t Magnetic Functions Beyond the Spin-Hamiltonian |b Texte imprimé |z 9783540811206 | |
| 776 | 0 | |0 097673226 |t Magnetic functions beyond the spin-Hamiltonian |f Volume Editor: D.M.P. Mingos |c Berlin |n Springer |d 2006 |p 1 vol. (276 p.) |s Structure and bonding |z 3-540-26079-X | |
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